Take your 4-6 Trap Darts and line them down a hall or near where you can see a Big Daddy, making sure the path he'll take towards you is amply covered. All that's required is Electrical Trap Darts (4-6 per Big Daddy). Once you've obtained the Dart Gun, you can try this technique. It will stumble across the Trap Bolts you've shot and die, since it only takes two of them to take one down. Then shoot a round with another weapon at the Big Daddy to anger it so it comes towards you. Give yourself about 20 feet (in-game, of course) and shoot your Trap Bolts so they hang between you and the location of the Big Daddy you want to kill. If you have Trap Bolts for your Crossbow, you can execute this technique to kill Big Daddies easily. This technique is especially useful on Bouncer class Big Daddies. Use the Electric Buck on your Shotgun, alternating between the buck and using the Electro Bolt Plasmid every few seconds (which will shock and freeze him in addition to dealing damage). Here's another technique to take out Big Daddies. After a few hits, between 1-3 health packs should lie on the floor for you to grab, for free.
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While you can buy health packs at health stations for $10, you can get them for free by simply smashing the machines with your wrench. It takes about 3/4 of a tank, but the Big Daddy won't be able to move as you shoot and kill him. Try using Electric Gel in the Chemical Thrower. Here's another easy method to kill Big Daddies easily. This method usually results in a one-hit kill and is especially useful against higher-level Splicers.
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(mode on the left, code to type in on the right) Note: Any active codes are disabled when a new area loads or intermission sequence plays. Then, press the corresponding key during game play to activate the corresponding cheat function. Set a key binding to the following codes (for example, "F10=fly"). Use a text editor to edit the "defuser.ini" file in the game directory. This procedure involves editing a game file create a backup copy of the file before proceeding. Search for the section called and find the unbound key that you want to use and bind it to the command "Exec upgrades.txt" (F7=Exec upgrades.txt). In “X:Documents and SettingsApplication DataBioshock” (XP) or “X:UsersAppDataRoamingBioShock” (Vista), open the file named “User.ini” - you need to enable viewing of hidden files and folders.